Chapter 1 Overview of Low-Volatile Gas 1.1 Characteristics of Low-Volatile Gas 1.2 Sources and Hazards of Low-Volatile Gas 1.3 Purification Technologies for Low-Volatile Gas References Chapter 2 Overview of Adsorption Purification Technology 2.1 Principles and Fundamentals of Adsorption Technology 2.2 Adsorption Phase Equilibrium 2.3 Adsorption Kinetics 2.4 Desorption Characteristics References Chapter 3 Overview of Adsorbents 3.1 Concept of Adsorbents 3.2 Microporous Adsorbents 3.2.1 Activated Carbon and Other Microporous Carbon Materials 3.2.2 Alumina 3.2.3 Silica Gel 3.2.4 Resins 3.2.5 Zeolites 3.3 Mesoporous Adsorbents 3.3.1 Ordered Mesoporous Silica 3.3.2 Ordered Mesoporous Carbon 3.3.3 Disordered Mesoporous Carbon References Chapter 4 Adsorption Equilibrium of Low-Volatility Gases on Adsorbent Materials 4.1 Relevant Experimental Methods 4.1.1 Gas-Phase PAHs Adsorption Experiments 4.1.2 Dioxin Adsorption Experiment 4.2 Adsorption Equilibrium of Low-Volatility Gases on Microporous Adsorbents 4.2.1 Adsorption Equilibrium of Gaseous PAHs on Microporous Adsorbents 4.2.2 Adsorption Equilibrium of Dioxins on Microporous Adsorbents 4.3 Adsorption Equilibrium of Low-Volatility Gases on Mesoporous Adsorbents 4.3.1 Adsorption Equilibrium of Gaseous PAHs on Ordered Mesoporous Adsorbents 4.3.2 Adsorption Equilibrium of Gaseous PAHs on Disordered Mesoporous Adsorbents 4.4 Factors Affecting Adsorption Equilibrium References Chapter 5 Adsorption Kinetics of Low-Volatility Gases on Adsorbent Materials 5.1 Related Experimental Methods 5.1.1 Axial Diffusion Adsorption Model 5.1.2 LDF Kinetic Model 5.1.3 Constant Concentration Wave Kinetic Model 5.1.4 Estimation of Adsorption Kinetic Parameters 5.2 Adsorption Kinetics of Low-Volatility Gases on Microporous Adsorbents 5.2.1 Adsorption Kinetics of Gas-Phase PAHs on Ordered Microporous Adsorbents 5.2.2 Adsorption Kinetics of Dioxins on Microporous Adsorbents 5.3 Adsorption Kinetics of Low-Volatility Gases on Mesoporous Adsorbents 5.3.1 Adsorption Kinetics of Gas-Phase PAHs on Ordered Mesoporous Adsorbents 5.3.2 Adsorption Kinetics of Gas-Phase PAHs on Disordered Mesoporous Adsorbents References Chapter 6 Desorption Characteristics of Low-Volatility Gases on Adsorption Materials
6.1 Relevant Experimental Methods 6.1.1 Temperature-Programmed Desorption (TPD) Experimental Method 6.1.2 Desorption Kinetic Analysis Method 6.2 Microporous Adsorbents 6.2.1 Desorption Characteristics of Gas-Phase PAHs on Microporous Adsorbents 6.2.2 Desorption Characteristics of Dioxins on Microporous Adsorbents 6.3 Mesoporous Adsorbents 6.3.1 Desorption Characteristics of Gas-Phase PAHs on Ordered Mesoporous Adsorbents 6.3.2 Desorption Characteristics of Gas-Phase PAHs on Disordered Mesoporous Adsorbents References Chapter 7 Adsorption Mechanism Based on Molecular Simulation 7.1 Relevant Experimental Methods 7.1.1 Grand Canonical Monte Carlo (GCMC) Method 7.1.2 Molecular Dynamics (MD) Method 7.1.3 Density Functional Theory (DFT) 7.2 Adsorption of PAHs on Mesoporous Silica-Based Models:GCMC and MD Simulation 7.2.1 Kinetic Simulation of PAHs Adsorption on Mesoporous Silica-Based Models 7.2.2 Thermodynamic Simulation of PAHs Adsorption on Mesoporous Silica-Based Models 7.2.3 Model Validation and Adsorption Performance of PAHs 7.2.4 Adsorption States of PAHs on Mesopore Models 7.3 DFT Simulation on the Adsorption of PAHs on Silica-Based Mesoporous Models 7.3.1 DFT Computational Simulation 7.3.2 Adsorption Configuration of PAHs 7.3.3 Interactions Between PAHs and Silica-Based Surfaces 7.4 DFT Simulation of PAH Adsorption on Disordered Mesoporous Carbon Models 7.4.1 DFT Calculation Simulation 7.4.2 Adsorption Mechanism of Phenanthrene/Pyrene on ECSC References Chapter 8 Potential Applications of Low-Volatile Gas Adsorption Purification 8.1 Purification of Low-Volatility Radioactive Gaseous Waste 8.1.1 Purification of Gaseous Iodine in Radioactive Emissions 8.1.2 Purification of RuO4 in Radioactive Gases 8.2 Adsorptive Purification of Polycyclic Aromatic Hydrocarbons (PAHs) in Coke Oven Flue Gas 8.3 Purification of Dioxins in Municipal Waste Incineration Flue Gas 8.4 Purification of Naphthalene and Nicotine in Cigarette Smoke 8.5 Adsorptive Purification of Indoor Low-Volatility Gaseous Pollutants 8.5.1 Purification of Macromolecular Gaseous Pollutants in the Coating Industry 8.5.2 Purification of Benzo [a] pyrene Carcinogens in Kitchen Fumes 8.6 Summary References