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低揮發性氣體吸附--材料機制與應用(英文版)(精)

  • 作者:李子宜//吳昊陽|責編:于水
  • 出版社:化學工業
  • ISBN:9787122496881
  • 出版日期:2026/03/01
  • 裝幀:精裝
  • 頁數:264
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內容大鋼
    在「碳達峰與碳中和」目標背景下,對鋼鐵廠等冶金爐窯、天然氣蒸汽重整等工業過程尾氣中菲、芘、?等低揮發性氣體進行吸附分離富集,實現它們作為有機化工重要原料的高值化資源利用,具有「經濟」和「環保」雙重意義。本書系統介紹了低揮發性氣體吸附分離的實際需求、技術發展趨勢、吸附劑選擇、典型工藝、分子模擬等;重點闡述了低揮發性氣體特性、來源與危害,吸附技術原理與基礎,分子模擬在吸附科學中的應用,低揮發性氣體在傳統介孔材料和新型介孔碳上的吸附相平衡及動力學、脫附特性,對吸附-脫附平衡機制進行了探討和分析。本書可供從事氣體吸附分離研究和應用的科技工作者以及相關專業的本科生、研究生閱讀參考。

作者介紹
李子宜//吳昊陽|責編:于水

目錄
Chapter 1 Overview of Low-Volatile Gas
  1.1  Characteristics of Low-Volatile Gas
  1.2  Sources and Hazards of Low-Volatile Gas
  1.3  Purification Technologies for Low-Volatile Gas
  References
Chapter 2 Overview of Adsorption Purification Technology
  2.1  Principles and Fundamentals of Adsorption Technology
  2.2  Adsorption Phase Equilibrium
  2.3  Adsorption Kinetics
  2.4  Desorption Characteristics
  References
Chapter 3 Overview of Adsorbents
  3.1  Concept of Adsorbents
  3.2  Microporous Adsorbents
    3.2.1  Activated Carbon and Other Microporous Carbon Materials
    3.2.2  Alumina
    3.2.3  Silica Gel
    3.2.4  Resins
    3.2.5  Zeolites
  3.3  Mesoporous Adsorbents
    3.3.1  Ordered Mesoporous Silica
    3.3.2  Ordered Mesoporous Carbon
    3.3.3  Disordered Mesoporous Carbon
  References
Chapter 4 Adsorption Equilibrium of Low-Volatility Gases on Adsorbent Materials
  4.1  Relevant Experimental Methods
    4.1.1  Gas-Phase PAHs Adsorption Experiments
    4.1.2  Dioxin Adsorption Experiment
  4.2  Adsorption Equilibrium of Low-Volatility Gases on Microporous Adsorbents
    4.2.1  Adsorption Equilibrium of Gaseous PAHs on Microporous Adsorbents
    4.2.2  Adsorption Equilibrium of Dioxins on Microporous Adsorbents
  4.3  Adsorption Equilibrium of Low-Volatility Gases on Mesoporous Adsorbents
    4.3.1  Adsorption Equilibrium of Gaseous PAHs on Ordered Mesoporous Adsorbents
    4.3.2  Adsorption Equilibrium of Gaseous PAHs on Disordered Mesoporous Adsorbents
  4.4  Factors Affecting Adsorption Equilibrium
  References
Chapter 5 Adsorption Kinetics of Low-Volatility Gases on Adsorbent Materials
  5.1  Related Experimental Methods
    5.1.1  Axial Diffusion Adsorption Model
    5.1.2  LDF Kinetic Model
    5.1.3  Constant Concentration Wave Kinetic Model
    5.1.4  Estimation of Adsorption Kinetic Parameters
  5.2  Adsorption Kinetics of Low-Volatility Gases on Microporous Adsorbents
    5.2.1  Adsorption Kinetics of Gas-Phase PAHs on Ordered Microporous Adsorbents
    5.2.2  Adsorption Kinetics of Dioxins on Microporous Adsorbents
  5.3  Adsorption Kinetics of Low-Volatility Gases on Mesoporous Adsorbents
    5.3.1  Adsorption Kinetics of Gas-Phase PAHs on Ordered Mesoporous Adsorbents
    5.3.2  Adsorption Kinetics of Gas-Phase PAHs on Disordered Mesoporous Adsorbents
  References
Chapter 6 Desorption Characteristics of Low-Volatility Gases on Adsorption Materials

  6.1  Relevant Experimental Methods
    6.1.1  Temperature-Programmed Desorption (TPD) Experimental Method
    6.1.2  Desorption Kinetic Analysis Method
  6.2  Microporous Adsorbents
    6.2.1  Desorption Characteristics of Gas-Phase PAHs on Microporous Adsorbents
    6.2.2  Desorption Characteristics of Dioxins on Microporous Adsorbents
  6.3  Mesoporous Adsorbents
    6.3.1  Desorption Characteristics of Gas-Phase PAHs on Ordered Mesoporous Adsorbents
    6.3.2  Desorption Characteristics of Gas-Phase PAHs on Disordered Mesoporous Adsorbents
  References
Chapter 7 Adsorption Mechanism Based on Molecular Simulation
  7.1  Relevant Experimental Methods
    7.1.1  Grand Canonical Monte Carlo (GCMC) Method
    7.1.2  Molecular Dynamics (MD) Method
    7.1.3  Density Functional Theory (DFT)
  7.2  Adsorption of PAHs on Mesoporous Silica-Based Models:GCMC and MD Simulation
    7.2.1  Kinetic Simulation of PAHs Adsorption on Mesoporous Silica-Based Models
    7.2.2  Thermodynamic Simulation of PAHs Adsorption on Mesoporous Silica-Based Models
    7.2.3  Model Validation and Adsorption Performance of PAHs
    7.2.4  Adsorption States of PAHs on Mesopore Models
  7.3  DFT Simulation on the Adsorption of PAHs on Silica-Based Mesoporous Models
    7.3.1  DFT Computational Simulation
    7.3.2  Adsorption Configuration of PAHs
    7.3.3  Interactions Between PAHs and Silica-Based Surfaces
  7.4  DFT Simulation of PAH Adsorption on Disordered Mesoporous Carbon Models
    7.4.1  DFT Calculation Simulation
    7.4.2  Adsorption Mechanism of Phenanthrene/Pyrene on ECSC
  References
Chapter 8 Potential Applications of Low-Volatile Gas Adsorption Purification
  8.1  Purification of Low-Volatility Radioactive Gaseous Waste
    8.1.1  Purification of Gaseous Iodine in Radioactive Emissions
    8.1.2  Purification of RuO4 in Radioactive Gases
  8.2  Adsorptive Purification of Polycyclic Aromatic Hydrocarbons (PAHs) in Coke Oven Flue Gas
  8.3  Purification of Dioxins in Municipal Waste Incineration Flue Gas
  8.4  Purification of Naphthalene and Nicotine in Cigarette Smoke
  8.5  Adsorptive Purification of Indoor Low-Volatility Gaseous Pollutants
    8.5.1  Purification of Macromolecular Gaseous Pollutants in the Coating Industry
    8.5.2  Purification of Benzo [a] pyrene Carcinogens in Kitchen Fumes
  8.6  Summary
  References

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