目錄
Chapter 1 Introduction
1.1 Science and Scientific Methods
1.2 Chemistry and Research
Chapter 2 Gases, Liquids, Solids, and Solutions
2.1 Simple Gas Laws and Ideal Gas Equation
2.2 Mixtures of Gases
2.3 Kinetic-Molecular Theory of Gases
2.4 Distribution of Molecular Speeds
2.5 Real Gases and van der Waals Equation
2.6 Properties of Liquids and Solids
2.7 Phase Transition and Phase Diagram
2.8 Properties of Solutions
Chapter 3 Thermochemistry and Chemical Equilibria
3.1 Some Terminologies in Thermochemistry
3.2 The First Law of Thermodynamics
3.3 Heats of Reaction and Enthalpy Change
3.4 Hess抯 Law and Standard Enthalpies of Formation
3.5 Spontaneity and the Concept of Entropy
3.6 Criteria for Spontaneous Change
3.7 Dynamic Equilibrium and the Equilibrium Constants
3.8 The Reaction Quotient and Le Ch鈚elier抯 Principle
3.9 Gibbs Free Energy Change and Equilibrium
Chapter 4 Chemical Kinetics
4.1 The Rate of a Chemical Reaction
4.2 Effect of Concentration on Reaction Rates: The Rate Laws
4.3 Order of Reaction
4.4 The Effect of Temperature on Reaction Rates
4.5 Theoretical Models of Chemical Kinetics
4.6 Reaction Mechanisms
4.7 Catalysis and Catalytic Chemistry
Chapter 5 Acid-Base Equilibria and Precipitation-Dissolution Equilibria
5.1 Theory of Acids and Bases
5.2 Self-Ionization of Water and the pH Scale
5.3 Ionization Equilibria of Acids and Bases
5.4 Common-Ion Effect and Buffer Solutions
5.5 Acid-Base Indicators and Titration
5.6 Solubility Product Constant and Its Relationship with Solubility
5.7 Criteria for Precipitation and Its Completeness
5.8 Dissolution and Transformation of Precipitates
5.9 Fractional Precipitation
Chapter 6 Redox Reactions and Electrochemistry
6.1 Some Terminologies in Redox Reactions
6.2 Electrode Potentials and Cell Potential
6.3 Standard Electrode Potentials and Standard Cell Potential
6.4 Relationship between el, G? and Redox Equilibrium Constant K
6.5 Potential Diagrams
6.6 Nernst Equation and Concentration Cells
6.7 Electrolytic Cells and Overpotential
6.8 Battery and Its Applications
Chapter 7 Atomic Structure
7.1 The Nuclear Atom
7.2 Quantum Theory
7.3 Atomic Spectra and Bohr Theory
7.4 The Nature of Microscopic Particles
7.5 Quantum Mechanical Model of Hydrogen-Like Species
7.6 Quantum Mechanical Results of Hydrogen-Like Species
7.7 Multielectron Species and Electron Configurations
7.8 The Periodic Law and the Periodic Table
7.9 Periodic Properties of the Elements
Chapter 8 Molecular Structure and Crystal Structure
8.1 Lewis Theory
8.2 Shape of Molecules
8.3 Polarity of Molecules
8.4 Valence-Bond Theory
8.5 Molecular Orbital Theory
8.6 Bonding in Metals and Band Theory
8.7 Intermolecular Forces
8.8 Crystal Structure
8.9 Various Types of Crystals and Their Structures
Chapter 9 Complex-Ion Equilibria and Coordination Compounds
9.1 Basic Concepts in Coordination Compound
9.2 Isomerism
9.3 Crystal Field Theory
9.4 Properties of Coordination Compounds
9.5 Complex-Ion Equilibria
9.6 Applications of Coordination Chemistry
Appendix
Appendix A Names of Chemical Compounds
Appendix B Table of Mathematical and Physical Constants
Appendix C Tables of Chemical Data
第1章 緒論
1.1 科學與科學方法
1.2 化學與科研
第2章 氣體、液體、固體和溶液
2.1 簡單氣體定律與理想氣體狀態方程
2.2 混合氣體
2.3 氣體分子運動論
2.4 氣體分子的速率分佈
2.5 實際氣體與范德華方程
2.6 液體和固體的性質
2.7 相變與相圖
2.8 溶液的性質
第3章 化學熱力學與化學平衡
3.1 化學熱力學的一些術語
3.2 熱力學第一定律
3.3 反應熱與焓變
3.4 蓋斯定律與標準生成焓
3.5 自發性與熵的概念
3.6 自發變化的判據
3.7 動態平衡與平衡常數
3.8 反應商與勒夏特列原理
3.9 吉布斯自由能變與平衡
第4章 化學動力學
4.1 化學反應速率
4.2 濃度對反應速率的影響：速率方程
4.3 反應級數
4.4 溫度對反應速率的影響
4.5 化學動力學理論模型
4.6 反應機理
4.7 催化作用與催化化學
第5章 酸鹼電離平衡與沉澱溶解平衡
5.1 酸鹼理論
5.2 水的自耦電離與pH
5.3 酸鹼電離平衡
5.4 同離子效應與緩衝溶液
5.5 酸鹼指示劑與酸鹼滴定
5.6 溶度積常數及其與溶解度的關係
5.7 沉澱生成與沉澱完全的判據
5.8 沉澱的溶解與轉化
5.9 分步沉澱
第6章 氧化還原反應與電化學
6.1 氧化還原反應的一些術語
6.2 電極電勢與電池電動勢
6.3 標準電極電勢與標準電池電動勢
6.4 E池、G與氧化還原平衡常數K的關係
6.5 元素電勢圖
6.6 能斯特方程與濃差電池
6.7 電解池與超電勢
6.8 電池及其應用
第7章 原子結構
7.1 核型原子
7.2 量子理論
7.3 原子光譜與玻爾理論
7.4 微觀粒子的特性
7.5 類氫物種的量子力學模型
7.6 類氫物種的量子力學結論
7.7 多電子物種與電子組態
7.8 元素周期律與元素周期表
7.9 元素性質的周期性
第8章 分子結構與晶體結構
8.1 路易斯理論
8.2 分子的形狀
8.3 分子的極性
8.4 價鍵理論
8.5 分子軌道理論
8.6 金屬鍵與能帶理論
8.7 分子間作用力
8.8 晶體結構
8.9 各種晶體類型及其結構
第9章 配位解離平衡與配合物
9.1 配合物的基本概念
9.2 異構現象
9.3 晶體場理論
9.4 配合物的性質
9.5 配位解離平衡
9.6 配位化學的應用
附錄
附錄A 化合物的命名
附錄B 數理常數表
附錄C 化學數據表
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