目錄
CHAPTER 1 Introduction
1.1 Concept of Spectroscopy
1.2 Concept of Photonics and Plasmonics
1.3 Concept of Plasmon-Enhanced Spectroscopy
1.3.1 Plasmon-enhanced fluorescence
1.3.2 Plasmon-enhanccd Resonance fluorescence energy transfer
1.3.3 Surface-enhanced Raman scattering
1.3.4 The remote-excitation of SERS
1.3.5 Tip-enhanced Raman scattering spectroscopy
1.3.6 Remote excitation-TERS microscopy
1.3.7 Plasmon-enhanced coherence anti-Stokes Raman
scattering images
References
CHAPTER 2 Molecular Spectroscopy
2.1 Jablonski Diagram
2.2 Electronic State Transition
2.2.1 Ultraviolet-visible-near IR absorption spectroscopy
2.2.2 Two-photon absorption spectroscopy
2.2.3 Fluorescence spectroscopy
2.2.4 Fluorescence resonance energy transfer
2.3 Vibration spectroscopy
2.3.1 Raman spectroscopy
2.3.2 Infrared spectroscopy
2.3.3 Modes of molecular vibration
2.3.4 The difference between Raman and spectra
2.4 Rotational State
2.5 Electronic and Vibrational Spectroscopy by Circularly Polarized Light
2.5.1 Electronic circular dichroism
2.5.2 Raman optical activity
References
CHAPTER 3 Photonics and Plasmonics
3.1 Introduction
3.2 Exciton
3.2.1 Brief introduction of excitons
3.2.2 Exciton classification
3.3 Polariton
3.3.1 Brief introduction of polariton
3.3.2 Polariton types
3.4 Plasmon and surface plasmons
3.4.1 Plasmons
3.4.2 Surface plasmons
3.4.3 Surface plasmon polaritons
3.5 Plasmon-Exciton Coupling.Plexciton
References
CHAPTER 4 2D Borophene excitons
4.1 Introduction
4.2 Monolayer borophene
4.2.1 Monolayer borophene on Ag(111)
4.2.2 Monolayer borophene on Al(111)
4.2.3 Monolayer borophene on Ir(111)
4.2.4 Monolayer borophene on Au(111)
4.2.5 Monolayer borophene on Cu(111)
4.3 Bilayer borophene
4.3.1 Bilayer borophene on Ag(111)
4.3.2 Bilayer borophene synthesis on Cu(111)
4.4 Borophene heterostructure
4.4.1 Borophene-PTCDA lateral heterostructure
4.4.2 Borophene-Black phosphorus heterostructure
4.4.3 2D/1D borophene-graphene nanoribbons heterostructure
4.4.4 Borophene-graphene heterostructure
References
CHAPTER 5 Surface Piasmons
5.1 Brief Introduction of SPs
5.2 Physical Mechanism of SPs
5.2.1 Drude model
5.2.2 Relationship between Refractive Index and Dielectric Constant
5.2.3 Dispersion relations
5.3 Localized SPs
5.3.1 LSPs in metallic nanosphere
5.3.2 LSPs in coupled metallic NPs.parallel-polarized excitation
5.3.3 LSPs in coupled metallic NPs: vertical-polarized excitation
5.3.4 Plexciton model: coupling between plasmon and exciton
5.3.5 Fano Resonant Propagating Plexcitons and Rabi-splitting Local Plexcitons
5.3.6 Plexciton revealed in experiment
5.3.7 LSPs in coupled metallic NPs.many-body
5.4 Plasmonic Waveguide
5.4.1 The EM theory for calculating nanowires
5.4.2 The decay rate in the plasmon mode
5.4.3 The spontaneous emission near the nanotip
5.4.4 SPP modes of Ag NW by One-End Excitation
5.4.5 Optical non-reciprocity with multiple modes based on a hybrid metallic NW
5.4.6 Strongly enhanced propagation and non-reciprocal properties of CdSe NW
5.5 Unified treatments for LSPs and PSPs
5.6 Plexciton in TERS and in PSPs
References
CHAPTER 6 Plasmon-Enhanced Fluorescence Spectroscopy
6.1 The principle of plasmon-enhanced fluorescence
6.2 Plasmon-Enhanced Upconversion Luminescence
6.2.1 Brief introduction
6.2.2 Physical principle and mechanism
6.3 Principle of Plasmon-Enhanced FRET
References
CHAPTER 7 Plasmon-Enhanced Raman Scattering Spectra
7.1 Surface-Enhanced Raman Scattering Spectroscopy
7.1.1 Brief history of SERS spectroscopy
7.1.2 Physical mechanism of SERS spectroscopy
7.2 Tip-Enhanced Raman Scattering Spectroscopy
7.2.1 Brief introduction of TERS spectroscopy
7.2.2 Physical mechanism of TERS spectroscopy
7.2.3 Setup of TERS
7.3 Remote-Excitation SERS
References
CHAPTER 8 High-Vacuum Tip-Enhanced Raman Scattering Spectroscopy
8.1 Brief Introduction
8.1.1 Brief description of setup of HV-TERS
8.1.2 Detailed description of setup of HV-TERS
8.2 The Application of HV-TERS Spectroscopy in in situ Plasmon-Driven Chemical Reactions
8.3 Plasmonic Gradient Effect
8.4 Plasmonic Nanoscissors
References
CHAPTER 9 Physical Mechanism of Plasmon-Exciton Coupling Interaction
9.1 Brief Introduction of Plexcitons
9.2 Plasmon-Exciton Coupling Interaction
9.2.1 Strong plasmon-exciton coupling interaction
9.2.2 Application of strong plasmon-exciton coupling interaction
9.2.3 Weak plasmon-exciton coupling interaction
9.2.4 Application of weak plasmon-exciton coupling interaction
9.2.5 Plexcitons
9.3 Application
9.3.1 Plasmonic electrons-enhanced resonance Raman scattering and electrons-enhanced fluorescence spectra
9.3.2 Tip-enhanced photoluminescence spectroscopy
9.3.3 Femtosecond pump-probe transient absorption spectroscopy
References
CHAPTER 10 Plasmon-Exciton-Co-Driven Surface Catalysis Reactions
10.1 Plasmon-Exciton-Co-Drivcn Surface Oxidation Catalysis Reactions
10.2 Plasmon-Exciton-Co-Driven Surface Reduction Catalysis Reactions
10.3 Unified Treatment for Plasmon-Exciton-Co-Driven Oxidation and Reduction Reactions
References
CHAPTER 11 Nonlinear Optical Microscopies of CARS,TPEF,SHG, SFG and SRS
11.1 Principles of Nonlinear Optical Microscopies
11.2 Applications of Nonlinear Optical Microscopies
11.2.1 Optical characterizations of 2D materials
11.2.2 Highly efficient photocatalysis of g-C3N4
11.2.3 Optical characterizations of 3D materials
11.2.4 Advances of biophotonics
11.2.5 MSPR-enhanced nonlinear optical microscopy
References
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