內容大鋼
This book provides an overview of plasticizers, from the latest global research developments to the laws and regulations applied to their use. In addition the book details the author's recently developed methodology for a catalytic hydrogenation ot phthalate plasticizers. It presents insights into the development of the catalytic phthalate hydrogenation from the reaction mechanism and catalyst characterization to pilot tests and its industrialization. Given its scope, the book will appeal to a broad readership, particularly professionals at universities and scientific research institutes, as well as practitioners in industry.
目錄
1 Introduction
1.1 Background
1.2 Fundamentals of Plasticizers
1.2.1 Symbols and Abbreviations
1.2.2 Major Functions of Plasticizers
1.2.3 Major Performance-Determining Factors for Plasticizers
1.2.4 Mechanism for Plasticity Increase by Plasticizers
1.2.5 Property Requirements for Plasticizers
1.2.6 Inspection Standards for Plasticizers
1.2.7 Types of Plasticizers
1.3 Cyclohexane-1， 2-Dicarboxylate Plasticizers
1.4 Environmentally Friendly Plasticizers
1.5 Developmental Direction of Plasticizer Industry in China
1.6 Main Contents of This Book
References
2 Foreign and Domestic Plasticizer Laws
2.1 Foreign Plasticizer Laws， Evolution
2.2 Domestic Plasticizer Laws and Evolution
2.3 Interpretations of Foreign and Domestic Plasticizer Laws
2.3.1 EU Bans
2.3.2 EU』s REACH Policy [1，2]
2.3.3 The EU』s RoHS [1，3]
2.3.4 USA』s CPSIA
2.3.5 Related Phthalate Laws in Other Countries
2.3.6 Domestic Laws [4–6]
2.4 Comparison and Trend of Plasticizer Laws for Food Contact Applications
2.4.1 Current Status
2.4.2 Chinese Laws and Regulations
2.4.3 EU』s Laws and Regulations
2.4.4 USA』s Laws and Regulations
2.5 Conclusion
References
3 Current Status of Plasticizer Research
3.1 Foreign Research Status
3.1.1 Phthalate Hydrogenation Technology
3.1.2 Research on Toxicity of Phthalate Compounds
3.2 Domestic Research Status
3.2.1 Synthesis of DIBCH(1999)[9]
3.2.2 Synthesis of HHPA(2000)[10]
3.3 Di(2-Propylheptyl) Phthalate (2006) [13]
3.3.1 Physical Properties
3.3.2 Performance
3.4 Cyclohexane Dicarboxylate Plasticizers (2010)[14]
3.4.1 Preparation of Cyclohexane Dicarboxylate Plasticizers
3.4.2 Properties and Assessment of Cyclohexane Dicarboxylate Plasticizers
3.4.3 Application Examples of Formulation
3.4.4 Conclusion
3.5 Development Status of Plasticizers (2010， 2011) [18，19]
3.5.1 Status of Plasticizers in Foreign Countries
3.5.2 Status of Plasticizers in China
3.5.3 New Environmentally Friendly Plasticizers
3.5.4 Sustainable Development of Plasticizers in China
3.6 Diisononyl Cyclohexane-1，2-Dicarboxylate(2010，2014)[20，21]
3.6.1 Physical Properties
3.6.2 Production Routes of DINCH
3.6.3 Applications of DINCH
3.7 Environmentally Friendly Plasticizers
3.7.1 Di(2-Ethylhexyl) Cyclohexane-1，2-Dicarboxylate Plasticizer(2011)[22]
3.7.2 Research and Application Progress of Catalytic Synthesis of Environmentally Friendly Plasticizers(2012)[15]
3.7.3 Innovations and Applications of Green Plasticizers[97]
3.7.4 Technological Innovation and Market Dynamics of Green Plasticizers(2017)[98]
3.8 Hydrogenation of Dioctyl Phthalate (2012)[34]
3.9 Liquid-Phase Catalytic DOP Hydrogenation and Kinetics(2012)[50]
3.10 Synthesis and Application of Environmentally Friendly DEHCH Plasticizer(2013)[38，113，114]
3.11 Synthesis and Application of Environmentally Friendly DEHCH Plasticizer(2014–2015)
3.11.1 Preparation of DOP Hydrogenation Catalyst(2014)[120]
3.11.2 DEHP Hydrogenation Product Analysis Using GC-MC (2015)[42]
3.12 Synthesis of DEHCH via Direct Esterification (2015)[121]
3.13 Cable Industry』s Response to EU』s Newest Environmental Laws
3.14 Applications of Environmentally Friendly Plasticizers in Disposable Gloves(2016)[127]
3.15 Development and Application of Environmentally Friendly Polyester Plasticizers (2016)[128]
3.16 How to Accurately Assess and Use Benzoate-Based Plasticizers?(2016)[129]
3.17 Production Study of Environmentally Friendly DEHCH Plasticizer(2016)[130]
3.18 Co-existing Opportunities and Challenges for DOP Market(2017)[115]
3.19 Conclusion
References
4 Foreign and Domestic Inventions and Patents
4.1 Foreign Inventions and Patents
4.1.1 Hydrogenation Methods
4.1.2 Esterification Methods
4.2 Domestic Inventions and Patents
4.2.1 A Catalyst for Hydrogenating Dimethyl Terephthalates to Dimethyl Cyclohexane-1，4-Dicarboxylates and the Preparation
Thereof(2001)[11]
4.2.2 A Plasticizer Containing Cyclohexane Multi-carboxylate and its Preparation Method(2006)[12]
4.2.3 A Catalyst for Preparing Cyclohexane-1，2-Dicarbolxylates(2008)[13]
4.2.4 A Method for Preparing Cyclohexane-1，2-Dicarboxylates (2008)[14]
4.2.5 A Method for Preparing Environmentally Friendly Di(2-ethylhexyl) Cyclohexane-1，2-Dicarboxylate(DEHCH)(2009)[15]
4.2.6 A Method for Preparing Environmentally Friendly Di(2-ethylhexyl) Cyclohexane-1，2-Dicarboxylate(DEHCH)Plasticizer(2011)[16]
4.2.7 A Method for Preparing Cyclohexane-1，2-Dicarboxylates Using Organic Acid Catalysts(2010)[17]
4.2.8 A Method for Preparing Cyclohexane- 1,2-Dicarboxylates Using Ionic Liquid Catalysts (2010) [18]
4.2.9 A Type of Catalysts for Hydrogenating Benzenecarboxylates to Cyclohex
4.2.19 An Integrated Method for Preparing Cyclohexane- 1,2-Dicarboxylates (2015)
4.2.20 A Type of Efficient Plasticizer Hydrogenation Catalysts and their Preparation Method (2013)
4.2.21 A Type of Non-linear Plasticizers and the Preparation and Applications Thereof (2013)
4.2.22 A Type of Apparatus for Preparing Dioctyl Cyclohexane- 1,4-Dicarboxylate (2013)
4.2.23 The Esterification Reaction Protocols for DOTP Plasticizer (2015)
4.2.24 A Method for Preparing Cyclohexane- 1,2-Dicarboxylates (2015)
4.2.25 A Method for Preparing Environmentally Friendly Plasticizers (2015)
4.2.26 A Method for Preparing Hexahydrophthalic Anhydride (2016)
4.2.27 A Method for Preparing Dioctyi Cyclohexane- 1,4-Dicarboxylate (2016)
4.2.28 A Method for Preparing the Catalysts used for Preparing Cyclohexane Dicarboxylates (2016)
4.3 Conclusion
References
5 Catalytic Ring Hydrogenation of Phthalate Plastieizers
5.1 Ring Hydrogenation of Phthalates
5.1.1 Experimental
5.1.2 Effects of Various Factors
5.1.3 Effects of S Content in DOP
5.1.4 Qualitative Analysis of Products
5.1.5 Separation and Purification of Products
5.1.6 Repeatability of Catalytic Hydrogenation
5.1.7 Conclusions
5.2 Multi-phase Catalysis Kinetics of DOP Hydrogenation
5.2.1 Effects of Concentration on DOP Hydrogenation Rate
5.2.2 Arrhenius Equation of Phthalate Hydrogenation Reaction
5.2.3 Conclusions
5.3 Characterizations of Catalysts
5.3.1 XRD
5.3.2 Tem
5.3.3 Texture Analysis of Catalysts
5.3.4 XPS
5.4 Reaction Mechanisms of Catalytic Phthalate Hydrogenation
5.5 Characterizations of PVC Plasticized by Cyclohexane-1,2-Dicarboxylates and Phthalates
5.5.1 Mechanical Properties of PVC/DEHCH and PVC/DOP Composite Materials
5.5.2 Thermal Properties of PVC/DEHCH and PVC/DOP Composite Materials
5.5.3 Dynamic Mechanical Analysis of PVC/DEHCH and PVC/DOP Composite Materials
5.5.4 Rheology of PVC/DOP and PVC/DEHCH Composite Materials
5.5.5 Solvent Extraction Resistance of PVC Samples with Different DEHCH and DOP Contents
5.5.6 Evaporation Resistance of PVC Composite Materials with Different DEHCH and DOP Contents
5.5.7 Photonic Properties of PVC Composite Materials with Different DEHCH and DOP Contents
5.5.8 Conclusions
5.6 Third-Party Inspections
5.6.1 Physico-Chemical Property Inspection for Ring-Hydrogenated Products
5.6.2 Toxicity Test of Ring Hydrogenation Product
5.6.3 Ring-Hydrogenated Product Pellets and PVC Articles
References
6 Pilot Demo and Industr
6.2.3 Separation and Purification System
6.2.4 Catalyst Recycling System
6.2.5 Exhaust Recycling System
6.3 Industrial Catalyst Production
6.4 Industrial Standards of Cyclohexane-Based Plasticizers
6.4.1 Scope
6.4.2 Normative References
6.4.3 Test Methods
6.4.4 Inspection Rules
6.4.5 Industrial Standard Numbers and Technical Index
6.5 Third-Party Inspections
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