目錄
Chapter 1 Coligative Properties of Diute Solution
1.1 The Composition Scales of Mixture
1.1.1 Mass Fraction,Volume Fraction and Mass Concentration
1.1.2 The Mole Fraction
1.1.3 The Amount-of-Substance Concentration and Molality
1.2 Vapor Pressure Lowering
1.2.1 The Vapor Pressure of Liquid
1.2.2 Vapor Pressure Lowering-Raoult's Law
1.3 Boiling Point Elevation and Freezing Point Depression
1.3.1 Boiling Point Elevation and Freezing Point Depression of Solution
1.3.2 Coligative Properties of Electrolyte Dilute Solution
1.4 Osmotic Pressure of Solution
1.4.1 Osmosis and Osmotic Pressure
1.4.2 The Relationship between Osmotic Pressure of Solution and Concentration
Temperature of Solution
1.4.3 Application of Osmotic Pressure in Medicine
Summary
Exercises
Supplementary Exercises
Chapter 2 The Basis of Chemical Thermodynamics
2.1 Thermodynamic System and State Function
2.1.1 System and Its Surroundings
2.1.2 State Functions and Process
2.1.3 Heat and Work
2.2 Energy Conservation and Heat of Chemical Reaction
2.2.1 Themodynamic Energy and the First Law of Thermodynamic
2.2.2 Enthalpy Change and Isobar Heat
2.2.3 Extent of Reaction,Equation of Them-Chemistry and Standard state
2.2.4 Hess's Law and Calculation of Reaction Heat
2.3 Entropy and Gibbs's Free Energy
2.3.1 Spontaneous Process and Its Characteristics
2.3.2 Entropy of A System
2.3.3 Gibbs's Free Energy of System
Summary
Exercises
Supplementary Exercises
Chapter 3 Chemical Equilibrium
3.1 The Extent of Chemical Reaction and Standard Equilibrium Constant
3.1.1 The Standard Equilibrium Constant
3.1.2 Predicting Reaction Direction by Standard Equilibrium Constant Ke
3.2 Experimental Equilibrium Constant
3.3 The Shift of Chemical Equilibrium
3.3.1 Effect of A Change in Concentration
3.3.2 Effect of A Change in Pressure
3.3.3 Effect of A Change in Temperature
Summary
Exercises
Supplementary Exercises
Chapter 4 Rate of Chemical Reaction
4.1 Chemical Reaction Rate and Its Expression
4.1.1 The Rate of Chemical Reaction
4.1.2 Average Rate and Instantaneous Rate of A Chemical Reaction
4.2 The Effect of Concentration on Reaction Rate
4.2.1 Rate Law of Chemical Reaction
4.2.2 Characteristics with the Simple Reaction Order
4.3 Brief Introduction for Rate Theory of Chemical Reaction
4.3.1 Collision Theory and Activation Energy
4.3.2 Brief Introduction of Transition State Theory
4.4 The Effect of Temperature on Chemical Reaction
4.4.1 The Relationship between Temperature and Rate Constant-Arthenius Equation
Chapter 5 Electrolyte solutions
Chapter 6 Buffer Solution
Chapter 7 Equilibria of slightly Soluble lonic Compounds
Chapter 8 Oxidation-Reduction Reaction and Electrode Potential
Chapter 9 Atomic Structure and Periodic Law
Chapter 10 Covalent Bond and intermolecular
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