《高分子化學原理》一書成書較早，作者是高分子界享有盛名的1974年度諾貝爾化學獎獲得者P. J. 弗洛里。經過長達半個多世紀的考驗，該書已經成為公認的高分子化學經典教科書，培養了幾代高分子科學家。本書系高校化學及相關專業高分子科學入門教材，儘管未包括聚合物力學性質和高分子動力學或動態性質等方面的內容，但對聚合反應及反應動力學以及高分子溶液性質等均有系統討論。
作者介紹
(美)P.J.弗洛里
目錄
Preface CHAPTER I HISTORICAL INTRODUCTION 1.Early Investigations on Naturally Oecurring Polymers 2.Early Encounters with Condensation Polymers.. 3.Vinyl Polymers 4.Rise of the Macromolecular Hypothesis References.. CHAPTER II TYPES OF POLYMERIC SUBSTANCES:DEFINITIONS AND CLASSIFICATIONS 1.Primary Definitions 2.Classification of Polymers 3.Condensation Polymers and Condensation Polymerization. 4.Addition Polymers from Unsaturated Monomers 5.Polymerization of Cyclic Compounds. 6.Anomalous Condensation Polymerizations 7.Inorganic Polymers 8.Concluding Remarks on the Structure and Properties of High Polymers. References. CHAPTDR III MOLECULAR SIZE AND CHEMICAL REACTIVITY; PRINCIPLES OF CONDENSATION POLYMERIZATION 1.Chemical Reactivity in Homologous Series of Monomeric Compounds 2.Theory of the Reactivity of Large Molecules 3.Kinetics of Condensation Polymerization 4.Kinetics of Degradation of Condensation Polymers 4a.Hydroliysis of Cellulose and Cellulose Derivatives 4b.Hydrolysis of Polyamides. 4c.Alcoholysis of Polyesters 4d.Interchange Reactions in Condensation Polymers 5.Molecular Weights of Linear Condensation Polymers 6.Ring Formation s.Chain Polymerization 7.Summary and Conclusions:The Principle of Equal Reactivity of All Funetional Groups. References..、 CHAPTER IV POLYMERIZATION OF UNSATURATED MONOMERS BY FREE RADICAL MECHANISMS 1.The Conversion of Monomer to Polymer 1a.Kinetic Scheme for Polymerization in the Presence of an 1b.Dependence of Initial Rates on the Coneentrations of Initiator and Monomer 1c.Initiator Efficiencies 1d.Evaluation of Parameters . 1e.The Course of the Conversion of Monomer to Polymer;Autoacceleration 1f.Kinetics of Thermal Polymerization 2.Chain Lengths 2a.Kinetic Chain Length and Degree of Polymerization 2b.Kinetics of Chain Transfer. 2c.Chain Transfer in Undiluted Monomer;Evaluation of Parameters 2d.Chain Transfer with Solvents 2e.Dependence of the Degree of Polymerization on Temperature 2f.Regulators 3.Absolute Values of the Rate Constants for Individual Steps, 3a.Methods for Determining the Mean Lifetime of an Active Center. 8b.Experimental Results 4.Inhibition and Retardation of Polymerization 4a.Reaction Mechanisms
4b.Kinetics of Inhibition and Retardation 4c.Allylic Polymerization;Autoinhibition References. …… CHAPTER V COPOLYMERIZATION,EMULSION POLYMERIZATION AND IONIC POLYMERIZATION CHAPTER VI THE STRUCTURE OF VINYL POLYMERS CHAPTER VII DETERMINATION OF MOLECULAR WEIGHTS CHAPTER VIII MOLECULAR WEIGHT DISTRIBUTIONS IN LINEAR POLYMERS CHAPTER IX MOLECULAR WEIGHT DISTRIBUTIONS IN NONLINEAR POLYMERS AND THE THEORY OF GELATION CHAPTER X CONFIGURATION OF POLYMER CHAINS CHAPTER XI RUBBER ELASTICITY CHAPTER XII STATISTICAL THERMODYNAMICS OF POLYMER SOLUTIONS CHAPTER XIII PHASE EQUILIBRIA IN POLYMER SYSTEMS CHAPTER XIV CONFIGURATIONAL AND FRICTIONAL PRORERTIES OF THE POLYMER MOLECULE IN DILUTE SOLUTION GLOSSARY OF PRINCIPAL SYMBOLS. AUTHOR INDEX SUBJECT INDEx
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