CHAPTER 1 Introduction CHAPTER 2 SP-Driven Oxidation Catalytic Reactions 2.1 SP-Driven Oxidation Catalytic Reactions by SERS in Atmosphere Environment 2.1.1 Genuine SERS Spectrum of PATP 2.1.2 SP-Driven Oxidation Catalytic Reactions of PATP 2.1.3 SP-Driven Oxidation Catalytic Reactions on Metal/Semiconductor Hybrids 2.2 SP-Driven Oxidation Catalytic Reactions by SERS in Aqueous Environment 2.3 SP-Driven Oxidation Catalytic Reactions by TERS in Ambient Environment 2.4 SP-Driven Oxidation Catalytic Reactions by TERS in HV Environment CHAPTER 3 SP-Driven Reduction Catalytic Reactions 3.1 SP-Driven Reduction Catalytic Reactions in Atmosphere Environment 3.1.1 SP-Driven Reduction Catalytic Reactions by SERS in Atmosphere Environment 3.1.2 SP-Driven Reduction Catalytic Reactions on Metal/Semiconductor Hybrids 3.2 SP-Driven Reduction Catalytic Reactions by SERS in Aqueous Environment 3.2.1 Setup of Electrochemical SERS 3.2.2 Potential-Dependent Plasmon Driven Sequential Chemical Reactions 3.2.3 pH-Dependent Plasmon Driven Sequential Chemical Reactions 3.2.4 Electrooptical Tuning of Plasmon Driven Double Reduction Interface Catalysis 3.3 The Stability of Plasmon Driven Reduction Catalytic Reactions in Aqueous and Atmosphere Environment 3.4 SP-Driven Reduction Catalytic Reactions by TERS 3.4.1 SP-Driven Reduction Catalytic Reactions by TERS in Ambient Environment 3.4.2 SP-Driven Reduction Catalytic Reactions by TERS in HV Environment 3.4.3 Plasmon Hot Electrons or Thermal Effect on SP-Driven Reduction Catalytic Reactions in HV Environment CHAPTER 4 Photo- or Plasmon Induced Oxidized and Reduced Reactions CHAPTER 5 The Priority of Plasmon Driven Reduction or Oxidation Reactions 5.1 Plasmon Driven Diazo-Coupling Reactions in Atmosphere Environment 5.1.1 Characterization of SERS and Graphene-Mediated SERS Substrate 5.1.2 Selective Reduction Reactions of PNA on the Ag NPs in Atmosphere Environment 5.1.3 Selective Reduction Reactions of PNA on the Surface of G-Ag NPs Hybrids in Atmosphere Environment 5.1.4 Hot Electron-Induced Reduction Reactions of PNA on G-Ag NWs Hybrids in Atmosphere Environment 5.2 The Priority of Plasmon Driven Reduction or Oxidation in Aqueous Environment 5.3 The Priority of Plasmon Driven Reduction or Oxidation in HV Environment CHAPTER 6 Plasmon Exciton Coupling Interaction for Surface Catalytic Reactions 6.1 Plasmon Exciton Coupling Interaction for Surface Oxidation Catalytic Reactions 6.1.1 Characterization of Ag NPs-TiO2 Film Hybrids 6.1.2 Ag NPs-TiO2 Film Hybrids for Plasmon Exciton Codriven Surface Oxidation Catalytic Reactions 6.1.3 Plasmon Exciton Coupling of Ag NPs-TiO2 Film Hybrids Studied by SERS Spectroscopy 6.1.4 Plasmon Exciton Coupling of Ag NPs-TiO2 Film Hybrids for Surface Oxidation Catalytic Reactions under Various Environments 6.2 Plasmon Exc 7.2 Physical Mechanism on Plasmon Exciton Coupling Interaction Revealed by Femtosecond Pump-Probe Transient Absorption Spectroscopy CHAPTER 8 Electrically Enhanced Plasmon Exciton Coupling Interaction for Surface Catalytic Reactions 8.1 Electrooptical Synergy on Plasmon Exciton-Codriven Surface Reduction Catalytic Reactions 8.1.1 Plasmon Exciton Coupling Interaction of Monolayer G-Ag NPs 8.1.2 Electrical Properties of Plasmon Exciton Coupling Device 8.1.3 Plasmon Exciton-Codriven Surface Reduction Catalytic Reactions 8.1.4 Bias-Voltage-Dependent Plasmon Exciton Codriven Surface Reduction Catalytic Reactions 8.1.5 Gate-Voltage-Dependent Plasmon Exciton Codriven Surface Reduction Catalytic Reactions 8.2 Electrically Enhanced Hot Hole Driven Surface Oxidation Catalytic Reactions CHAPTER 9 Piasmon Waveguide Driven Chemical Reactions 9.1 Plasmon Waveguide for Remote Excitation 9.1.1 Features of Remote Excitation SERS and Early Application 9.1.2 Remote Excitation Plasmon Driven Chemical Reactions 9.2 Remote Excitation Polarization-Dependent Surface Photochemical Reactions by Plasmon Waveguide 9.3 Remote-Excitation Time-Dependent Surface Catalytic Reactions by Plasmon Waveguide CHAPTER 10 Plasmon Driven Dissociation 10.1 Resonant Dissociation of Surface Adsorbed Molecules by Plasmonic Nanoscissors 10.2 Plasmonic Nanoscissors for Molecular Design 10.3 Plasmon Driven Dissociation of H2 10.3.1 Plasmon Driven Dissociation of H2 on Au 10.3.2 Plasmon Driven Dissociation of H2 on Aluminum Nanocrystal 10.4 Plasmon Driven Dissociation of N2 10.5 Plasmon Driven Water Splitting 10.5.1 Plasmon Driven Water Splitting under Visible Illumination 10.5.2 An autonomous photosynthetic device of Plasmon Driven Water Splitting 10.6 Plasmon Driven Dissociation of CO2 10.7 Real-Space and Real-Time Observation of a Plasmon Induced Chemical Reactions of a Single Molecule 10.8 Competition between Reactions and Degradation Pathways in Plasmon Driven Photochemistry CHAPTER 11 Summary and Outlook Acknowledgements References